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                                                 Kamco Limited  

                                  MATERIAL SAFETY DATA SHEET  



                                                NEUTRALISING CRYSTALS  



                                                                                                      Revision8: date:  01/07/2017  



Section 1: Identification of the substance/mixture and of the company undertaking  



          

          1.1. Product identifier  



                                          Product name:         NEUTRALISING CRYSTALS  

                                  REACH registered no:    01-2119485498-19-XXXX  

                                                   CAS no:      497-19-8  

                                               EINECS no:       207-838-8  

                                                                  



          1.2. Relevant identified uses of the substance or mixture and uses advised against  



                          Use of substance / mixture:           Neutralising of acidic descaling products before disposal.  



          1.3. Details of the supplier of the safety data sheet  



                                        Company name:           Kamco Ltd  

                                                                Unit 9, Curo Park  

                                                                Frogmore  

                                                                St Albans  

                                                                Herts  

                                                                AL2 2DD  



                                                        Tel:    01727 875020  



                                                        Fax:    01727 875335  



                                                     Email:     info@kamco.co.uk  



          1.4. Emergency telephone number  



                                                  Emergency tel: 01727 875020  



Section 2: Hazards identification  



 

          2.1. Classification of the substance or mixture  



                            Classification under CLP:           Eye Irrit. 2 – H319  

                                                                  

                           Classification under CHIP:           Xi;R36

                                                              



                    Most important adverse effects:             Causes serious eye irritation.  



          2.2. Label elements  



                          Label elements under CLP:               



                                    Hazard statements:          Causes serious eye irritation.  



                                           Signal words:        Warning  



                                    Hazard pictograms:          GHS07: Exclamation mark  



                                                                                   

                                 


                                                                            

                                Precautionary statements:                   P264: Wash hands thoroughly after handling.  

                                                                            P280: Wear protective gloves/protective clothing/eye  

                                                                            protection/face protection.  

                                                                            P305/351/338: IF IN EYES: Rinse cautiously with water for  

                                                                            several minutes.  Remove contact lenses, if present and  

                                                                            easy to do.  Continue rinsing.  

                                                                            P337+313: If eye irritation persists, get medical  

                                                                            advice/attention.  



 



            2.3. Other hazards  



                                                  Other hazards:            Hygroscopic: readily absorbs water from air.  

                                                                 PBT:       This substance is not identified as a PBT substance  



 

Section 3: Composition/information on ingredients  



3.2. Mixtures  



  SODIUM CARBONATE  

     EINECS                 CAS               CHIP Classification                              CLP Classification                                Percent  

   207-838-8             497-19-8                      Xi: R36                                              -                                           



Section 4: First aid measures  



          

            4.1. Description of first aid measures  



                                                    Skin contact:           Remove contaminated clothing immediately and wash skin  

                                                                           with soap and water.  Get medical attention if any discomfort  

                                                                            continues.  

                                                     Eye contact:           Immediately flush with plenty of water for up to 15 minutes.   

                                                                            Remove any contact lenses and open eyes wide apart. Get  

                                                                            medical attention if any discomfort continues.  

                                                         Ingestion:         Provide rest, warmth and fresh air.  Immediately rinse mouth  

                                                                            and drink plenty of water (200-300 ml).  Get medical attention  

                                                                            if any discomfort continues.  

                                                        Inhalation:         Move exposed person into fresh air at once.  Get medical  

                                                                            attention if any discomfort continues.  



            4.2. Most important symptoms and effects, both acute and delayed  



                                                    Skin contact:           Slightly irritating.  



                                                     Eye contact:           Irritating to eyes.  



                                                         Ingestion:         May cause discomfort if swallowed.  



                                                        Inhalation:  

                                                                            May cause irritation to the respiratory systems.  



                             Delayed / immediate effects:                   Immediate effects can be expected after short-term  

                                                                            exposure.  



            4.3. Indication of any immediate medical attention and special treatment needed  



                          Immediate / special treatment:                    Eye bathing equipment should be available on the premises.  



Section 5: Fire-fighting measures  

            



            5.1. Extinguishing media  



                                                                            Use fire-extinguishing media appropriate for surrounding  

                                        Extinguishing media:  

                                                                            materials.  
                                                                      



           5.2. Special hazards arising from the substance or mixture  



                                                                     The product does not support combustion. If heated emits  

                                        Exposure hazards:  

                                                                     toxic fumes of carbon dioxide/monoxide.  



           5.3. Advice for fire-fighters  



                                 Advice for fire-fighters:           Self-contained breathing apparatus and full protective  

                                                                     clothing must be worn in case of fire.  



Section 6: Accidental release measures  

          



           6.1. Personal precautions, protective equipment and emergency procedures  



                                   Personal precautions:             Follow precautions for safe handling described in this safety  

                                                                     data sheet.  



           6.2. Environmental precautions  



                           Environmental precautions:                Do not discharge in to drains or rivers.  



           6.3. Methods and material for containment and cleaning up  



                                    Clean-up procedures:             Remove spillage with vacuum cleaner.  If not possible, collect  

                                                                     spillage with shovel, broom or the like.  Flush area with plenty  

                                                                     of water.  



           6.4. Reference to other sections  



                          Reference to other sections:               Refer to section 8 of MSDS  



Section 7: Handling and storage  

        



           7.1. Precautions for safe handling  



                                 Handling requirements:              Avoid spilling, skin and eye contact.  Provide good  

                                                                     ventilation.  



           7.2. Conditions for safe storage, including and incompatibilities  



                                      Storage conditions:            Keep containers tightly closed.  Store in dry, ventilated area  

                                                                     away from materials which react with alkalis.  Keep in original  

                                                                     container.  

                                      Suitable packaging:            Plastic tubes or pails.  



           7.3. Specific end use(s)  



                                     Specific end uses(s):           Neutralising of acidic descaling products before disposal.  





Section 8: Exposure controls/personal protection  

          



           8.1. Control parameters  



                                                                            

           8.2. Exposure controls  



                                  Engineering measures:              Ensure there is sufficient ventilation of the area.  



                                  Respiratory protection:            Avoid breathing dust.  No specific recommendation made,  

                                                                     but protection against nuisance dust must be used when the  

                                                                     general level exceeds 10mg/m3.  



                                           Hand protection:          Protective gloves.  



                                             Eye protection:         Safety goggles/face shield are recommended.  





                                                   Skin protection:              Protective clothing (e.g. rubber apron/rubber footwear)  





Section 9: Physical and chemical properties  

           



            9.1. Information on basic physical and chemical properties  



                                                                    State:       Crystalline powder, dust.  



                                                                 Colour:         White  



                                               Solubility in water:              Soluble in water.  



                                                                        pH:      >11 (10%)  



                  Solubility value (g/100g H2O@20ºC):                            26  

                                                                                   

                                                    Relative density:            2.5 g/ml @ 20C  



            9.2. Other information   



Section 10: Stability and reactivity  



             

             10.1. Reactivity  



                                                            Reactivity:                                                                                  



             10.2. Chemical stability  



                                               Chemical stability:               Stable under normal temperature conditions and  

                                                                                 recommended use.  



             10.3. Possibility of hazardous reactions  



                                          Hazardous reactions:                   Avoid exposure to moisture and humid atmospheres to  

                                                                                 prevent caking.  



             10.4. Conditions to avoid  



                                            Conditions to avoid:  

                                                                                 Avoid excessive heat for prolonged periods of time.  



             10.5. Incompatible materials  



                                               Materials to avoid:               Strong acids, acid anhydrides, and aluminium.  



             10.6. Hazardous decomposition products  



                                      Haz. decomp. products:                     Oxides of carbon    



Section 11: Toxicological information  



              



             11.1. Information on toxicological effects  



  Toxicity values:  

           Route                    Species                       Test                            Value                           Units  



             IHL                       RAT                       LC50                             2300                           mg/m3  



            ORL                        RAT                       LD50                             2800                           mg/kg  



        DERMAL                         RBT                       LD50                            >2000                           mg/kg  



 

                                                                                        

   Relevant hazards for substance:                                                                                               

                        Hazard                                        Route                                                Basis  

     Serious eye damage/irritation                                     OPT                                               Xi: R36    



               

             Symptoms / routes of exposure  



                                                            Skin contact:               Slightly irritating.  



                                                              Eye contact:              Irritating to eyes.  



                                                                  Ingestion:            May cause discomfort if swallowed.  



                                                                 Inhalation:          May cause irritation to respiratory system.  

                                                                                        



                                  Delayed / immediate effects:   Immediate effects can be expected after short-term     exposure.  



 



Section 12: Ecological information  



               



              12.1. Toxicity  



              Ecotoxicity values:                                                                                                                     

                       Species                                          Test                             Value                                  Units  

                      DAPHNIA                                48H EC50                                  200-227                                   mg/l  



 



 

 



              12.2. Persistence and degradability  



                              Persistence and degradability:                             



              12.3. Bioaccumulative potential  



                                    Bioaccumulative potential:                           



              12.4. Mobility in soil  



                                                                     Mobility:          The product is soluble in water.  



              12.5. Results of PBT and vPvB assessment  



                                                   PBT identification:                  This substance is not identified as a PBT substance .  



              12.6. Other adverse effects  



                                                                                        Spillage in sewers or waterways must be avoided. Large  

                                            Other adverse effects:  

                                                                                        doses cause high pH which may affect effluent and sewage.  



 



Section 13: Disposal considerations  



               



              13.1. Waste treatment methods  



                                               Disposal operations:                    Waste to be treated as controlled waste.  Disposal to  

                                                                                        licensed waste disposal site in accordance with local Waste  

                                                                                        Disposal Authority.  In small quantities, dispose of by flushing  

                                                                                        away with copious amounts of water or slowly neutralising  

                                                                                       with acid to neutral pH.  Neutralisation generates heat.  

                                           Disposal of packaging:  

                                                                                         



                                                                             NB:        The user’s attention is drawn to the possible existence of  

                                                                                        regional or national regulations regarding disposal.  



Section 14: Transport information  



                                                       Transport class:                 This product is not classified for transport.  



Section 15: Regulatory information  



             



            15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture  



                                      Statutory instruments:               Not applicable.  



                              Approved Code of Practice:                   Safety Data Sheets for Substances and Preparations.   

                                                                           Classification and Labelling of Substances and Preparations  

                                                                           Dangerous for Supply.  

 

Section 16: Other information  



 

                                            Other information:  

                                                                             

                                                                          

                                                                             

                                              Legal disclaimer:            The above information is believed to be correct but does not  

                                                                           purport to be all-inclusive and shall be used only as a guide.   

                                                                           Kamco Limited shall not be held liable for any damage  

                                                                           resulting from handling or from contact with the above  

                                                                           product.  

 


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